1146966-01-9Relevant academic research and scientific papers
Chemoselective reactions of 3-Benzyloxy-1,2-o-Quinone with organometallic reagents
Pettus, Thomas R. R.,Miller, Luke A.,Marsini, Maurice A.
supporting information; experimental part, p. 1955 - 1958 (2009/09/25)
Chemoselective additions of organometallic reagents to 3-benzyloxy-1,2-o- quinone are described. Various nucleophiles are shown to undergo selective 1,2-addition, 1,4-addition, and etherification. Selective 1,2-additions provide stable, nondimerizing o-quinols as a novel alternative to oxidative dearomatization.
