114701-68-7

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 4364-06-1 (E)-cinnamaldehyde dimethylacetal 
• 24808-73-9 (E)-(3-methoxyprop-1-en-1-yl)benzene 
• 98-86-2 acetophenone 

Relevant academic research and scientific papers

One-pot enol silane formation-Mukaiyama aldol-type addition to dimethyl acetals mediated by TMSOTf

(Chemical Equation Presented) Various ketones, esters, amides, and thioesters add in high yield to dimethyl acetals in the presence of silyl trifluoromethanesulfonates and an amine base. Acetals derived from aryl, unsaturated, and aliphatic aldehydes are

Chemoselective aldol reaction of silyl enolates catalyzed by Mgl2 etherate

(matrix presented) Mukaiyama-type aldol coupling of typical silyl enolates 2-4 with aryl or vinyl aldehydes and acetals was realized in the presence of 1-5 mol % of MgI2 etherate (1) in a mild, efficient, and highly chemoselective manner. Iodid

Polymer-supported dicyanoketene acetal as a π-acid catalyst: Monothioacetalization and carbon-carbon bond formation of acetals

Polymeric dicyanoketene acetals (DCKA) were synthesized by copolymerization of styrene and divinylbenzene or ethylene glycol dimethacrylate. These novel polymers could be used successfully as recyclable π-acid catalysts in monothioaCetalization or carbon-carbon bond forming reaction of acetals.

Carbon-carbon bond formation and reduction of aldehydes, ketones and acetals with silylated nucleophiles catalysed by tetracyanoethylene

Tetracyanoethylene catalyses the reactions of aldehydes, ketones and acetals with silylated nucleophiles such as trimethylsilyl cyanide, allyltrimethylsilane, aryl methyl ketone trimethylsilylenol ethers and triethylsilane to promote carbon-carbon bond formation and reduction under neutral conditions.All the evidence strongly suggested that the reactions occur through single electron transfer (SET) mechanism based on UV spectroscopic measurements.

Catalytic Activity of Tetracyanoethylene in the Reactions of Aldehydes, Ketones and Acetals with Silylated Nucleophiles

Tetracyanoethylene catalyses the reactions of aldehydes, ketones and acetals with silylated carbon and hydrogen-nucleophiles to promote carbon-carbon bond formation and reduction under neutral conditions.

Efficient Activation of Acetals, Aldehydes, and Imines toward Silylated Nucleophiles by the Combined Use of Catalytic Amounts of 2 and TMS-CN under Almost Neutral Conditions

In the presence of catalytic amount of a transition metal compound such as 2, Co(acac)2, or NiCl2, trimethylsilyl cyanide smoothly reacts with acetals to form α-methoxy carbonitriles in good yields.In the coexistence of catalytic amounts of Rh

Efficient Activation of Acetals toward Nucleophiles with 2 Catalyst. New Method for the Preparation of Aldols from Acetals and Silyl Enol Ethers by the Combined Use of Catalytic Amounts of 2 and Trimethylsilyl Cyanide

In the presence of a catalytic amount of 2, di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium, trimethylsilyl cyanide smoothly reacts with acetals derived from aliphatic, unsaturated and aromatic aldehydes to form the corresponding α-cyano derivativ

New Method for Oxidative Carbon-carbon Bond Formation by the Reaction of Allyl Ethers, 2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ) and Silyl Carbon Nucleophiles

Allyl ethers are oxidized by DDQ to generate the corresponding cationic species, which in turn react with silyl carbon nucleophiles in the presence of a catalytic amount of lithium perchlorate to afford the coupled products in a one-pot procedure in good