114716-38-0Relevant academic research and scientific papers
Stereoselective Synthesis of Alcohols, XXVII Addition of (α-Chlorocrotyl)boronates to Aldehydes
Hoffmann, Reinhard W.,Dresely, Stefan,Lanz, Joachim W.
, p. 1501 - 1508 (2007/10/02)
(Z)-(α-Chlorocrotyl)boronates 3 add to nonchiral aldehydes to give homoallyl alcohols 5 with a syn-β-positioned methyl group and an (E)-chloroalkenyl unit.The diastereoselectivity in fafour of 5 is around 90percent.The corresponding (E)-(α-chlorocrotyl)bo
