114718-06-8

Basic information

• Product Name: rel-(1S,2S,9aR)-2,3,9,9a-tetrahydro-9,9-dimethyl-9a-phenyl-1H-pyrrolo<1,2-a>indole-1,2-dicarboxylate
• CAS NO: 114718-06-8
• Molecular Weight: 379.456
• Mol File: 114718-06-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: rel-(1S,2S,9aR)-2,3,9,9a-tetrahydro-9,9-dimethyl-9a-phenyl-1H-pyrrolo<1,2-a>indole-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: rel-(1S,2S,9aR)-2,3,9,9a-tetrahydro-9,9-dimethyl-9a-phenyl-1H-pyrrolo<1,2-a>indole-1,2-dicarboxylate(114718-06-8)
• EPA Substance Registry System: rel-(1S,2S,9aR)-2,3,9,9a-tetrahydro-9,9-dimethyl-9a-phenyl-1H-pyrrolo<1,2-a>indole-1,2-dicarboxylate(114718-06-8)

Safety Data

• Hazardous Substances Data: 114718-06-8(Hazardous Substances Data)

Upstream product

• 6636-32-4 3,3-dimethyl-2-phenyl-3H-indole 
• 64035-64-9 Trimethylsilylmethyl trifluoromethanesulfonate 
• 624-49-7 dimethylfumarate 

Relevant articles and documents

Generation and Characterization of Transient 3H-Indolium-methanides

Transient 3H-indolium-methanides 3a-d have been generated from the corresponding 2-substituted 3H-indoles 1a-d by the N-(trimethylsilyl)methylation/desilylation method. 3a,b were trapped by dimethyl maleate and dimethyl fumarate stereospecifically.All ylides add dimethyl ethynedicarboxylate to form 9,9a-dihydro-3H-pyrroloindoles 11a-d, out of which 11c,d (R = 9a-alkoxy) readily eliminate the corresponding alkanols to form 12.In the absence of dipolarophiles, 1a is predominantly transformed into Fischer base 14, whereas 3b gives rise to an unsymmetrical dimer 16.