114739-25-2Relevant academic research and scientific papers
A Radical Substitution on Sulfur of Thioester Group. Formation of β- and γ-Thiolactone
Tada, Masaru,Matsumoto, Mitsuhiro,Nakamura, Tatsuya
, p. 199 - 202 (1988)
Alkyl radicals having (t-butylthio)carbonyl group on β- or γ-position gave β- or γ-thiolactones whereas the homologous radical did not give δ-thiolactone.These reactions involve intramolecular radical substitution on the sulfur atom of thioester group.Ethylthioesters have much less reactivity to the same substitution.
Photolyses of Organocobaloxime Having Aralkyl and (Alkylthio)carbonyl Groups on the β-Position. A Radical Reaction Involving the Thioester Group
Tada, Masaru,Nakamura, Tatsuya,Matsumoto, Mitsuhiro
, p. 4647 - 4652 (2007/10/02)
-4-mesityl-2-methylbutyl>cobaloxime (1), -2-(ethoxycarbonyl)-5-phenylpentyl>cobaloxime (2), and -4-mesitylbutyl>cobaloxime (3) were photolyzed to produce pairs of organo radicals and
