Chemistry Letters p. 199 - 202 (1988)
Update date:2022-07-29
Topics:
Tada, Masaru
Matsumoto, Mitsuhiro
Nakamura, Tatsuya
Alkyl radicals having (t-butylthio)carbonyl group on β- or γ-position gave β- or γ-thiolactones whereas the homologous radical did not give δ-thiolactone.These reactions involve intramolecular radical substitution on the sulfur atom of thioester group.Ethylthioesters have much less reactivity to the same substitution.
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Doi:10.1021/jo900204e
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(2017)Doi:10.1016/S0040-4039(00)95592-8
(1987)
