114744-89-7Relevant academic research and scientific papers
New Odorless Protocols for the Synthesis of Aldehydes and Ketones from Thiol Esters
Miyazaki, Tohru,Han-Ya, Yuki,Tokuyama, Hidetoshi,Fukuyama, Tohru
, p. 477 - 480 (2007/10/03)
Dodecanethiol esters derived from odorless dodecanethiol proved to be suitable substrates for Pd-catalyzed reduction with triethylsilane, coupling with organozinc reagents, and coupling with terminal acetylenes.
A novel ketone synthesis by a palladium-catalyzed reaction of thiol esters and organozinc reagents
Tokuyama, Hidetoshi,Yokoshima, Satoshi,Yamashita, Tohru,Fukuyama, Tohru
, p. 3189 - 3192 (2007/10/03)
A variety of ketones have been prepared by a palladium-catalyzed reaction of ethanethiol esters with organozinc reagents. Various functional groups, including esters, ketones, aromatic halides and aldehydes, tolerate the reaction conditions. The reaction can also be applied to the synthesis of α-amino ketones using the corresponding L-α-amino thiol esters without racemization.
A NEW FACILE DIASTEREOCONVERSION OF 2-AMINO ALCOHOLS INVOLVING A NOVEL CYCLOCARBAMATION
Kano, Shinzo,Yokomatsu, Tsutomu,Iwasawa, Haruo,Shibuya, Shiroshi
, p. 6331 - 6334 (2007/10/02)
A new practical method for diastereoconversion of 2-amino alcohols was performed by treatment on N-Cbz- derivatives with trifluoromethanesulfonic anhydride or thionyl chloride, followed by ring cleavage of the resulting oxazolidin-2-ones
