1147459-05-9Relevant academic research and scientific papers
Rhodium-catalyzed dehydroborylation of styrenes with Naphthalene-1,8- diaminatoborane [(dan)BH]: New synthesis of masked β-borylstyrenes as new phenylene-vinylene cross-coupling modules
Iwadate, Noriyuki,Suginome, Michinori
supporting information; experimental part, p. 558 - 560 (2010/10/01)
Styrene derivatives underwent dehydroborylation with naphthalene-1,8- diaminatoborane [(dan)BH] in the presence of a cationic rhodium complex, giving β-borylstyrene derivatives in good yields. Thus prepared β-borylstyrenes bearing a chlorine or B(pin) group on their aromatic rings were utilized for the synthesis of highly conjugated molecules through stepwise cross-coupling, taking advantage of the dan group as an effective protective group for a boronyl group.
Synthesis of B-protected β-styrylboronic acids via iridium-catalyzed hydroboration of alkynes with 1,8-naphthalenediaminatoborane leading to iterative synthesis of oligo(phenylenevinylene)s
Iwadate, Noriyuki,Suginome, Michinori
supporting information; experimental part, p. 1899 - 1902 (2009/09/30)
Hydroboration of aromatic and aliphatic alkynes with 1,8- naphthalenediaminatoborane ((dan)BH) proceeded in the presence of [IrCl(cod)]2 complex with a DPPM or DPEphos ligand, affording alkenylboronic acids whose boronyl groups are masked by th
