2715-43-7

Basic information

• Product Name: 4-VINYL-BENZOIC ACID ETHYL ESTER
• Synonyms: ETHYL 4-VINYLBENZOATE;4-VINYL-BENZOIC ACID ETHYL ESTER;Benzoic acid, 4-ethenyl-, ethyl ester;4-ethenyl-Benzoic acid ethyl ester
• CAS NO: 2715-43-7
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21
• Product Categories: Aromatic Esters
• Mol File: 2715-43-7.mol
• Article Data: 40

Chemical Properties

• Boiling Point: 270.1°C at 760 mmHg
• Flash Point: 122.5°C
• Appearance: /
• Density: 1.037g/cm³
• Vapor Pressure: 0.00696mmHg at 25°C
• Refractive Index: 1.543
• CAS DataBase Reference: 4-VINYL-BENZOIC ACID ETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: 4-VINYL-BENZOIC ACID ETHYL ESTER(2715-43-7)
• EPA Substance Registry System: 4-VINYL-BENZOIC ACID ETHYL ESTER(2715-43-7)

Safety Data

• Hazardous Substances Data: 2715-43-7(Hazardous Substances Data)

Usage

General Description

4-Vinyl-benzoic acid ethyl ester, also known as ethyl 4-vinylbenzoate, is a chemical compound with the molecular formula C11H12O2. It is mainly used as a monomer in the production of polymers and as a precursor in the synthesis of various pharmaceuticals and fine chemicals. 4-Vinyl-benzoic acid ethyl ester is a clear, colorless to pale yellow liquid with a pungent odor and is slightly soluble in water but soluble in organic solvents. It is important to handle this chemical with care as it may cause irritation to the eyes and skin upon contact, and inhalation of its vapors may cause respiratory irritation.

InChI:InChI=1/C11H12O2/c1-3-9-5-7-10(8-6-9)11(12)13-4-2/h3,5-8H,1,4H2,2H3

Upstream product

• 348-06-1 p-carboethoxybenzenediazonium tetrafluoroborate 
• 42409-05-2 vinyl nonafluorobutane-1-sulfonate 
• 51934-41-9 4-iodobenzoic acid ethyl ester 
• 5798-75-4 Ethyl 4-bromobenzoate 
• 79-10-7 acrylic acid 
• 2768-02-7 (vinyl)trimethoxylsilane 
• 92988-08-4 trivinylboroxin 
• 64-17-5 ethanol 
• 1076-96-6 methyl 4-vinylbenzoate 
• 637-69-4 4-Methoxystyrene 
• 125261-30-5 p-(ethoxycarbonyl)phenyl triflate 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 541-41-3 chloroformic acid ethyl ester 
• 26496-94-6 Ethyl 4-(bromomethyl)benzoate 

Downstream Products

• 107099-30-9 (E)-4-(2-trimethylsilanylvinyl)benzoic acid ethyl ester 
• 1446446-53-2 C₂₇H₃₄BNO₃ 
• 1446446-65-6 ethyl 4-((1E,3E)-6-acetoxy-3-phenyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexa-1,3-dienyl)benzoate 
• 1292817-44-7 1,3,5-tris[(1E)-2’-(4’’-benzoic acid)vinyl]benzene 
• 1446757-97-6 (E,E)-2,5-dimethoxy-1,4-bis[2-(4-(ethyl carboxylate)styryl)]benzene 
• 1451497-61-2 C₁₆H₂₄O₃Si 
• 1451498-96-6 C₂₆H₃₄O₅Si₂ 
• 155671-16-2 ethyl 4-(1-fluoroethyl)benzoate 

Relevant articles and documents

Synthesis, structure and characterization of two solvatochromic metal-organic frameworks for chemical-sensing applications

Two isostructural Zr and Hf metal-organic frameworks (PU-1 and PU-2) were constructed from a hitherto unreported anthracene-derived dicarboxylate ligand and inorganic [M6O4(OH)4(CO2)12] (M = Zr4+ or Hf4+) secondary building unit under solvothermal conditions. They crystallized in the cubic Fd3m space group with doubly interpenetrated fcu-c topology. PU-1 exhibited an eye-catching color change within different solvents (especially in water) and could be a solvatochromic sensing material for recognition of solvent molecules.

Nickel-Catalyzed Ligand-Free Hiyama Coupling of Aryl Bromides and Vinyltrimethoxysilane

We herein disclose the first Ni-catalyzed Hiyama coupling of aryl halides with vinylsilanes. This protocol uses cheap, nontoxic, and stable vinyltrimethoxysilane as the vinyl donor, proceeds under mild and ligand-free conditions, furnishing a diverse variety of styrene derivatives in high yields with excellent functional group compatibility.

Catalyst-Free Visible-Light-Mediated Iodoamination of Olefins and Synthetic Applications

Herein we report a catalyst- and metal-free visible-light-mediated protocol enabling the iodoamination of miscellaneous olefins. This protocol is characterized by high yields under environmentally benign reaction conditions utilizing commercially available substrates and a green and biodegradable solvent. Furthermore, the protocol allows for late-stage functionalization of bioactive molecules and can be scaled to gram quantities of product, which offers manifold possibilities for further transformations, including morpholine, piperidine, pyrrolidine, and aziridine synthesis.