Welcome to LookChem.com Sign In|Join Free

CAS

  • or

114861-57-3

Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methylsulfanylthiocarboxyoxy-3,4-dihydro-2H-pyran-4-yl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

114861-57-3 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 114861-57-3 Structure

  • Basic information

    1. Product Name: Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methylsulfanylthiocarboxyoxy-3,4-dihydro-2H-pyran-4-yl ester
    2. Synonyms: Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methylsulfanylthiocarboxyoxy-3,4-dihydro-2H-pyran-4-yl ester
    3. CAS NO:114861-57-3
    4. Molecular Formula:
    5. Molecular Weight: 454.684
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 114861-57-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methylsulfanylthiocarboxyoxy-3,4-dihydro-2H-pyran-4-yl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methylsulfanylthiocarboxyoxy-3,4-dihydro-2H-pyran-4-yl ester(114861-57-3)
    11. EPA Substance Registry System: Benzoic acid (2R,3S,4R)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methylsulfanylthiocarboxyoxy-3,4-dihydro-2H-pyran-4-yl ester(114861-57-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 114861-57-3(Hazardous Substances Data)

114861-57-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 114861-57-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,8,6 and 1 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 114861-57:
(8*1)+(7*1)+(6*4)+(5*8)+(4*6)+(3*1)+(2*5)+(1*7)=123
123 % 10 = 3
So 114861-57-3 is a valid CAS Registry Number.

114861-57-3Relevant articles and documents

Synthesis of a Structurally Modified Glycal. (-)-(2R,4S)-2-Methyl-2-vinyl-4-(benzyloxy)-3,4-dihydro-2H-pyran

Paquette, Leo A.,Oplinger, Jeffrey A.

, p. 2953 - 2958 (1988)

A synthetic procedure for the transformation of levoglucosan (4) to (-)-(2R,4S)-2-methyl-2-vinyl-4-(benzyloxy)-3,4-dihydro-2H-pyran (1) in 11 steps is described.The scheme relies on selective deoxygenation of the pair of α-hydroxyl groups, blocking of the β-hydroxyl, and formation of ester 16.The presence of the carboxylate group allows for stereocontrolled methylation of the enolate anion, conversion of ester to vinyl, and ultimate eliminative removal of the methoxyl substituent in methyl glycoside 25.This key transformation takes advantage of regioselective acetal cleavage by trimethylsilyl iodide and in situ dehydroiodination of the product so formed with hexamethyldisilazane.Certain unsuccessful attempts to form the α-lithio anion of 1 are also discussed.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 114861-57-3