114862-75-8Relevant academic research and scientific papers
A concise total synthesis of the aglycone of the gilvocarcins
Deshpande, Prashant P.,Martin, Olivier R.
, p. 6313 - 6316 (2007/10/02)
A brief and convergent synthesis of the aglycone of the gilvocarcins M and E (and formally V) involving, in the key step, a Pd-mediated intramolecular biaryl coupling, is reported.
On the Photobiology of the Gilvocarcins. Total Synthesis of Defucogilvocarcin V and a Related Photoactive Vinyl Phenol
McGee, Lawrence R.,Confalone, Pat N.
, p. 3695 - 3701 (2007/10/02)
Defucogilvocarcin V (4a) and the related vinyl phenol 5a are important for the study of the photonicking of DNA by gilvocarcin antibiotics such as 1.They have been synthesized from a common precursor, lactone 6a, which contains the complete carbon framewo
