114885-96-0Relevant academic research and scientific papers
Chiral and Achiral Formamidines in Synthesis. The First Asymmetric Route to (-)-Yohimbone and an Efficient Total Synthesis of (+/-)-Yohimbone
Meyers, A. I.,Miller, Donald B.,White, Franklin H.
, p. 4778 - 4787 (2007/10/02)
An asymmetric synthesis of (-)-yohimbone from chiral formamidines is presented.The synthetic pathway intercepts a previously reported route to yohimbenone (6) reported by Winterfeldt.An investigation of the -rearrangement involving iminium salts 8 an
