114896-84-3Relevant academic research and scientific papers
Understanding the reactivity of enol ether radical cations: Investigation of anodic four-membered carbon ring formation
Yamaguchi, Yusuke,Okada, Yohei,Chiba, Kazuhiro
, p. 2626 - 2638 (2013/04/23)
The reactivity of enol ether radical cations was investigated in anodic four-membered carbon ring formations, advancing the mechanistic understanding of these reactions. The mono-ring-containing aromatic cations were reduced through inter- or intramolecular electron transfer to give mono- or bis-ring-containing compounds, respectively. Small structural changes in the hydrocarbon linkers tethering two aromatic rings exerted a powerful effect on the efficiency of such electron transfer events.
METHOD OF PRODUCING EPOXY COMPOUNDS
-
Page/Page column 5, (2011/11/06)
Provided is a method of efficiently producing an epoxy compound from an allyl ether having an aromatic ring under mild conditions by using hydrogen peroxide as an oxidizing agent without using an organic solvent. The method of producing an epoxy compound comprises reacting an allyl ether having an aromatic ring with hydrogen peroxide to epoxidize a carbon-carbon double bond of an allyl group to thereby produce a corresponding epoxy compound having an aromatic ring, wherein water only is used as a solvent without using an organic solvent, and a tungsten compound, and a tertiary amine and/or a quaternary ammonium salt, are used as a reaction catalyst.
