1149347-37-4

Basic information

• Product Name: C₂₆H₃₂F₂O₆Si
• Synonyms: C₂₆H₃₂F₂O₆Si
• CAS NO: 1149347-37-4
• Molecular Weight: 506.619
• Mol File: 1149347-37-4.mol

Chemical Properties

• CAS DataBase Reference: C₂₆H₃₂F₂O₆Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₃₂F₂O₆Si(1149347-37-4)
• EPA Substance Registry System: C₂₆H₃₂F₂O₆Si(1149347-37-4)

Safety Data

• Hazardous Substances Data: 1149347-37-4(Hazardous Substances Data)

Upstream product

• 1014698-47-5 ethyl 2-(6-O-(tert-butyldiphenylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-2,2-difluoroacetate 

Downstream Products

• 1149347-38-5 C₂₆H₃₃F₂N₃O₆Si 

Relevant articles and documents

Approaches to the synthesis of CF2-analogues of 2-deoxy-2-aminoglycosides

The preparation of a fluorinated C-glycosidic analogue of a 2-deoxy-2-acetamido-d-altrose is described. The synthetic sequence involves the addition of a difluoroenoxysilane to a d-glucal, an epoxidation of the resulting unsaturated CF2-glycoside and a ring-opening reaction with TMSN3. An Overman rearrangement of the unsaturated intermediate is also described.