114948-16-2Relevant academic research and scientific papers
Generation, Characterization, and Reactivity of a CuII-Alkylperoxide/Anilino Radical Complex: Insight into the O-O Bond Cleavage Mechanism
Paria, Sayantan,Ohta, Takehiro,Morimoto, Yuma,Ogura, Takashi,Sugimoto, Hideki,Fujieda, Nobutaka,Goto, Kei,Asano, Kaori,Suzuki, Takeyuki,Itoh, Shinobu
, p. 10870 - 10873 (2015)
The reaction of [CuI(TIPT3tren) (CH3CN)]ClO4 (1) and cumene hydroperoxide (C6H5C(CH3)2OOH, ROOH) at -60°C in CH2Cl2 gave a CuII-alkylperoxide/anilino radical complex 2, the formation of which was confirmed by UV-vis, resonance Raman, EPR, and CSI-mass spectroscopy. The mechanism of formation of 2, as well as its reactivity, has been explored.
Halogenated anilines as novel natural products from a marine biofilm forming microalga
Baumeister, Tim U. H.,Staudinger, Mona,Wirgenings, Marino,Pohnert, Georg
, p. 11948 - 11951 (2019)
The toxic halogenated anilines 2,4,6-tribromoaniline, 2,4,6-trichloroaniline and their dibromochloro and bromodichloro derivatives were considered as compounds of exclusive synthetic origin. Labeling studies and kinetic experiments confirmed that these substances are also biosynthesized by a marine biofilm forming microalga. They represent a novel class of halogenated natural products.
