114969-03-8

Basic information

• Product Name: Benzene, [(1-fluoroethenyl)sulfonyl]-
• CAS NO: 114969-03-8
• Molecular Formula: C8H7FO2S
• Molecular Weight: 186.207
• Mol File: 114969-03-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-fluoroethenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-fluoroethenyl)sulfonyl]-(114969-03-8)
• EPA Substance Registry System: Benzene, [(1-fluoroethenyl)sulfonyl]-(114969-03-8)

Safety Data

• Hazardous Substances Data: 114969-03-8(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 1034144-29-0 (1,3-benzothiazol-2-ylsulfonyl)fluoromethyl phenyl sulfone 
• 108-98-5 thiophenol 
• 136370-30-4 Phenyl 2-chloro-1-fluoroethyl sulfide 
• 27998-60-3 chloroethyl phenyl sulfoxide 
• 141075-87-8 α-fluorovinyl phenyl sulfide 
• 125927-29-9 2-Chloro-1-fluoroethyl Phenyl Sulfone 
• 135789-87-6 phosphonic acid diethyl ester 
• 56069-39-7 diethyl phenylsulfonylmethylphosphonate 

Downstream Products

• 125927-33-5 2-<2-Fluoro-2-(phenylsulfonyl)ethyl>-1,4-dioxane 
• 114969-06-1 C₂₂H₁₇FO₂S 
• 125927-35-7 1-Fluoro-1-(phenylsulfonyl)-3-pentanol 
• 125217-84-7 (1S,2R,5S,6R)-6-Benzenesulfonyl-6-fluoro-8-methyl-8-aza-bicyclo[3.2.1]octan-2-ol 
• 125217-84-7 (1S,2S,5S,6R)-6-Benzenesulfonyl-6-fluoro-8-methyl-8-aza-bicyclo[3.2.1]octan-2-ol 
• 1424387-94-9 C₁₇H₁₇F₂N₅O₃ 
• 5535-48-8 PVS 
• 125927-34-6 1-Fluoro-1-(phenylsulfonyl)-3-pentanone 
• 114969-07-2 (1S,4S)-5-Benzenesulfonyl-5-fluoro-bicyclo[2.2.1]hept-2-ene 

Relevant articles and documents

Stereoselective synthesis of cis -2-fluorocyclopropanecarboxylic acid

A rhodium-catalyzed cyclopropanation of 1-fluoro-1-(phenylsulfonyl)ethylene and diazo esters is described as an effective method for the stereoselective synthesis of cis-2-fluorocyclopropanecarboxylic acid. This process provides an example of the cyclopro

Expedient synthesis of α-substituted fluoroethenes

A mild and efficient synthesis of 1-aryl-1-fluoroethenes from benzothiazolyl (aryl)fluoromethyl sulfones and paraformaldehyde, under DBU- or Cs2CO3-mediated conditions at room temperature, is described. A comparable diethyl fluoro(naphthalen-2-yl)methylphosphonate reagent does not react with paraformaldehyde under these mild conditions. The utility of the methodology for synthesis of terminal α-fluoroalkenes bearing electron-withdrawing functionalities is also shown.

Addition of α-Oxyradicals to 1-Fluoro-1-(phenylsulfonyl)ethylene

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