114972-46-2

Upstream product

• 114972-44-0 (2S,3S)-1-(benzyloxy)-4-[(tert-butyldimethylsilyl)oxy]-3-methylbutan-2-ol 
• 114972-45-1 (2S,3S)-4-[(tert-butyldimethylsilyl)oxy]-3-methylbutane-1,2-diol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1164192-58-8 (2E,5E,8E)-(4R,7S,12S,13R)-13-Benzyloxymethoxy-7-methoxy-4,8,12-trimethyl-4-(tetrahydro-pyran-2-yloxy)-tetradeca-2,5,8-trienoic acid methyl ester 
• 114972-67-7 (2E,5E,8E)-(4R,7S,12S,13R)-13-Benzyloxymethoxy-7-methoxy-4,8,12-trimethyl-4-(tetrahydro-pyran-2-yloxy)-tetradeca-2,5,8-trienoic acid 
• 114972-62-2 ((E)-(2R,7S,8R)-8-Benzyloxymethoxy-2-methoxy-3,7-dimethyl-non-3-enyloxy)-tert-butyl-dimethyl-silane 
• 114972-50-8 1-((2R,3R)-3-Benzyloxymethoxy-2-methyl-butane-1-sulfonyl)-4-methyl-benzene 
• 114972-64-4 (E)-(2R,7S,8R)-8-Benzyloxymethoxy-2-methoxy-3,7-dimethyl-non-3-enal 
• 114972-63-3 (E)-(2R,7S,8R)-8-Benzyloxymethoxy-2-methoxy-3,7-dimethyl-non-3-en-1-ol 
• 25129-91-3 (-)-albocycline 
• 114972-48-4 ((2S,3R)-3-Benzyloxymethoxy-2-methyl-butoxy)-tert-butyl-dimethyl-silane 
• 115016-22-3 (2S,3R)-3-Benzyloxymethoxy-2-methyl-butan-1-ol 
• 114972-49-5 ((1R,2R)-3-Bromo-1,2-dimethyl-propoxymethoxymethyl)-benzene 

Relevant academic research and scientific papers

Enantioselective total synthesis of ingramycin

An enantioselective total synthesis of the 14-membered macrolide antibiotic ingramycin, 1, is described. In a convergent approach three chiral fragments A,B and C are assembled, the allylic bromide A deriving its chirality from L-serine while the asymmetr

Studies toward the Total Synthesis of Tianchimycins A and B: Construction of the Complete C1-C16 Framework

A stereoselective synthesis of the complete C1-C16 framework of tianchimycins A and B is described. Key transformations include Horner-Wadsworth-Emmons, Evans aldol, Gilman's and stereoselective alkylation reactions.