1150111-83-3

Basic information

• Product Name: Rh₂((C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃)2((C₁₀H₆O)2PNHSO₂C₆H₄(CH₂)3CH₃)2
• CAS NO: 1150111-83-3
• Molecular Weight: 2314.12
• Mol File: 1150111-83-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rh₂((C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃)2((C₁₀H₆O)2PNHSO₂C₆H₄(CH₂)3CH₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: Rh₂((C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃)2((C₁₀H₆O)2PNHSO₂C₆H₄(CH₂)3CH₃)2(1150111-83-3)
• EPA Substance Registry System: Rh₂((C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃)2((C₁₀H₆O)2PNHSO₂C₆H₄(CH₂)3CH₃)2(1150111-83-3)

Safety Data

• Hazardous Substances Data: 1150111-83-3(Hazardous Substances Data)

Upstream product

• 1150111-89-9 Rh₂((C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃)2(C₇H₈)2 
• 1333-74-0 hydrogen 
• 12082-47-2 acetylacetonatobis(ethylene)rhodium(I) 
• 1037069-62-7 (C₁₀H₆O)2PNHSO₂C₆H₄(CH₂)3CH₃ 
• 1150592-91-8 (CH₃CH₂)3NH⁽¹⁺⁾*(C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃^(1-)=(CH₃CH₂)3NH(C₁₀H₆O)2PNSO₂C₆H₄(CH₂)3CH₃ 

Relevant articles and documents

Sulfonamido-phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis

(Chemical Equation Presented) Sulfonamido-phosphoramidite ligands lead to the formation of Rh-Rh dinuclear complexes through the anionic P-N- bridging character. The resulting "boat-shaped" dinuclear catalysts activate molecular H2 through a cooperative dinuclear endocyclic mechanism, resulting in one bridging and one classical hydride on the dinuclear complex. These new complexes are very active hydrogenation catalysts that operate via a new cooperative hydrogenation activation mechanism, as calculated with density functional theory, and they display unequaled high selectivities in the hydrogenation of hindered cyclicacetamidoalkenes.