1150112-10-9Relevant academic research and scientific papers
A Fourfold Benzodehydroannuleno-Fused Porphyrazine
K?rte, Fabian,Bruhn, Clemens,Faust, Rüdigger
, p. 1620 - 1624 (2015)
Four benzodehydroannulene subunits were implemented on a dibenzoquinoxalinopoprhyrazine core using efficient palladium-mediated alkyne coupling and oxidative acetylene coupling on phenanthrene dione precursors. Despite the significant amount of strain in system, as evidenced by X-ray analysis of an immediate precursor, porphyrazine assembly leads to an extended model for N-doped graphyne with photosensitizing properties.
Enantioselective relay catalytic cascade intramolecular hydrosiloxylation and mukaiyama aldol reaction
Wang, Pu-Sheng,Li, Kang-Nan,Zhou, Xiao-Le,Wu, Xiang,Han, Zhi-Yong,Guo, Rui,Gong, Liu-Zhu
supporting information, p. 6234 - 6238 (2013/07/05)
Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has been established to give synthetically useful products in high yields and with excellent ee (see scheme). Copyright
An extremely simple dibenzopentalene synthesis from 2-bromo-1- ethynylbenzenes using nickel(O) complexes: Construction of its derivatives with various functionalities
Kawase, Takeshi,Konishi, Akihito,Hirao, Yasukazu,Matsumoto, Kouzou,Kurata, Hiroyuki,Kubo, Takashi
experimental part, p. 2653 - 2661 (2009/12/03)
An extremely simple dibenzopentalene synthesis from readily available 2-bromo-1-ethynylbenzenes using a nickel(O) complex is described. Although the yields are moderate, the formation of three C-C bonds in a single process and the high availability of the
