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115118-03-1

cis-4-Methylthio-5,6-dihydro-3-phenyl-6-<(trimethylsilyl)methyl>-4H-1,2-oxazine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 115118-03-1 Structure

  • Basic information

    1. Product Name: cis-4-Methylthio-5,6-dihydro-3-phenyl-6-<(trimethylsilyl)methyl>-4H-1,2-oxazine
    2. Synonyms:
    3. CAS NO:115118-03-1
    4. Molecular Formula:
    5. Molecular Weight: 293.505
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 115118-03-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: cis-4-Methylthio-5,6-dihydro-3-phenyl-6-<(trimethylsilyl)methyl>-4H-1,2-oxazine(CAS DataBase Reference)
    10. NIST Chemistry Reference: cis-4-Methylthio-5,6-dihydro-3-phenyl-6-<(trimethylsilyl)methyl>-4H-1,2-oxazine(115118-03-1)
    11. EPA Substance Registry System: cis-4-Methylthio-5,6-dihydro-3-phenyl-6-<(trimethylsilyl)methyl>-4H-1,2-oxazine(115118-03-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 115118-03-1(Hazardous Substances Data)

115118-03-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 115118-03-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,5,1,1 and 8 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 115118-03:
(8*1)+(7*1)+(6*5)+(5*1)+(4*1)+(3*8)+(2*0)+(1*3)=81
81 % 10 = 1
So 115118-03-1 is a valid CAS Registry Number.

115118-03-1Downstream Products

115118-03-1Relevant articles and documents

Highly Diastereoselective Deprotonation and Substitution of Chiral 5,6-Dihydro-4H-1,2-oxazines

Hippeli, Claudia,Reissig, Hans-Ulrich

, p. 3884 - 3886 (1988)

Deprotonation of the chiral 1,2-oxazine 1 by n-butyllithium provides a carbanion which reacts highly diastereoselectively with electrophiles affording the substituted 1,2-oxazines 2.The overall substitution occurs under retention of configuration in most cases investigated.These remarkable results are in accord with recent ab initio calculations.

Lithiated 5,6-Dihydro-4H-1,2-oxazines: Synthesis, Highly Diastereoselective Reactions with Electrophiles, and Subsequent Transformations

Reissig, Hans-Ulrich,Hippeli, Claudia

, p. 115 - 127 (2007/10/02)

The 6-(trimethylsilyl)methyl-substituted 1,2-oxazine 1 can smoothly be deprotonated with n-butyllithium at C-4 to give a lithiated species which reacts with a variety of electrophiles to provide the new 1,2-oxazines 5-16 in good yields.Besides the prepara

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