1151546-49-4

Upstream product

• 6104-48-9 ethynyl(diphenyl)phosphine oxide 
• 1707-03-5 diphenyl-phosphinic acid 
• 6104-47-8 ethynyldiphenylphosphine 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 1151546-50-7 1-bromo-2-(diphenylphosphinoyl)cyclohexa-1,4-diene 
• 1151546-59-6 11-bromo-12-(diphenylphosphinoyl)-9,10-dihydro-9,10-ethenylanthracene 
• 1151546-60-9 5-bromo-6-(diphenylphosphinoyl)-9,9-diemthyl-1,2,3,4,4a,7-hexahydro-1,3-methanonaphthalene 
• 1151546-51-8 1-bromo-2-(diphenylphosphinoyl)-4,5-dimethylcyclohexa-1,4-diene 
• 54098-24-7 diphenyl(2-diphenylaminoethynyl)phosphine oxide 

Relevant academic research and scientific papers

Process-Controlled Regiodivergent Copper-Catalyzed Azide-Alkyne Cycloadditions: Tailor-made Syntheses of 4- And 5-Bromotriazoles from Bromo(phosphoryl)ethyne

We developed a regiodivergent syntheses of 4- and 5-bromo-substituted 1,2,3-triazoles in copper-catalyzed azide-alkyne cycloadditions (CuAACs) by taking advantage of bromo(phosphoryl)ethyne 1 as a bromoethyne equivalent. A one-shot dephosphorylative CuAAC

General Cu-Catalyzed Csp-S Coupling

Copper-catalyzed cross-coupling of thiols and bromoalkynes affords a mild, rapid, and selective Csp-S coupling with broad scope, enabling the use of aryl-, alkyl-, and silyl-substituted alkynyl coupling partners (38 total examples, 50-99percent yields). Importantly, the method enables the preparation of difficult-to-access bis-heteroatom-functionalized (S,S-, S,P-, and S,N-) alkynes.

Synthesis of Ph2P(O)-stabilized Ynamines via C(sp)-N bond formation and their dephosphorylative copper-catalyzed click reaction

A facile and versatile synthesis of ynamines via C(sp)-N bond formation was established. We installed an electron-withdrawing phosphoryl group onto the ynamines to isolate them by column chromatography. Phosphoryl ynamines were synthesized by treatment of

PHOSPHOROUS COMPOUND AND TRANSITION METAL COMPLEX THEREOF

The present invention provides a phosphorous compound represented by general formula (1), and transition metal complexes containing such phosphorous compounds as ligands: wherein R1 to R7, A, B, Y, and Z have the same meanings as those defined in the specification.

1-Bromo-2-(diphenylphosphinoyl)ethyne and 1-bromo-2-(p-tolylsulfinyl)ethyne: versatile reagents eventually leading to benzocyclotrimers

The title compounds form Diels-Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall res