1151854-85-1

Basic information

• Product Name: 4-(chloro(phenyl)methyl)-2,2-dimethyl-1,3-dioxane
• CAS NO: 1151854-85-1
• Molecular Weight: 240.73
• Mol File: 1151854-85-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(chloro(phenyl)methyl)-2,2-dimethyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(chloro(phenyl)methyl)-2,2-dimethyl-1,3-dioxane(1151854-85-1)
• EPA Substance Registry System: 4-(chloro(phenyl)methyl)-2,2-dimethyl-1,3-dioxane(1151854-85-1)

Safety Data

• Hazardous Substances Data: 1151854-85-1(Hazardous Substances Data)

Upstream product

• 1151854-81-7 4-chloro-4-phenylbutane-1,3-diol 
• 67-64-1 acetone 

Relevant articles and documents

Lewis acid-promoted electron transfer deoxygenation of epoxides, sulfoxides, and amine N-oxides: the role of low-valent niobium complexes from NbCl5 and Zn

A mild and operationally simple deoxygenation of epoxides, sulfoxides, and amine N-oxides is described using a sub-stoichiometric amount of low-valent niobium complexes generated in situ from commercially available NbCl5 and zinc dust. The deoxygenation proceeds by a reductive cleavage of polarized O-C/O-N/O-S bonds through a single electron transfer from zinc metal to the niobium-substrate complex due to the high oxophilic nature of the niobium species. The presence of adjacent radical-stabilizing groups is beneficial to epoxide substrates; however the similar prerequisite does not apply to sulfoxides and amine N-oxides, where a broad range of substrates are efficiently deoxygenated in excellent yields.