1151967-63-3Relevant articles and documents
Investigation of transition metal-catalyzed nitrene transfer reactions in water
Alderson, Juliet M.,Corbin, Joshua R.,Schomaker, Jennifer M.
supporting information, p. 5270 - 5273 (2018/04/30)
Transition metal-catalyzed nitrene transfer is a powerful method for incorporating new C–N bonds into relatively unfunctionalized scaffolds. In this communication, we report the first examples of site- and chemoselective C–H bond amination reactions in aq
Ligand-controlled, tunable silver-catalyzed C-H amination
Alderson, Juliet M.,Phelps, Alicia M.,Scamp, Ryan J.,Dolan, Nicholas S.,Schomaker, Jennifer M.
supporting information, p. 16720 - 16723 (2015/01/16)
The development of readily tunable and regioselective C-H functionalization reactions that operate solely through catalyst control remains a challenge in modern organic synthesis. Herein, we report that simple silver catalysts supported by common nitrogenated ligands can be used to tune a nitrene transfer reaction between two different types of C-H bonds. The results reported herein represent the first example of ligand-controlled and site-selective silver-promoted C-H amination.