115204-39-2Relevant academic research and scientific papers
Reaction of sulfonimidamide Anions with Electrophiles
Okuma, Kentaro,Koike, Tetsufumi,Ohta, Hiroshi
, p. 4190 - 4193 (2007/10/02)
The reaction of alkylsulfonimidamides with bases gave corresponding carboanions, which were allowed to react with carbonyl compounds to give (2-hydroxyalkyl)sulfonimidamides in good yields.When benzoic anhydride or chlorotrimethylsilane was treated with these anions, corresponding phenacylsulfonimidamides or (trimethylsilyl)methylsulfonimidamides were obtained.On the other hand, the reaction of methyl N-p-tosylsulfonimidmorpholide anion with carbonyl compounds afforded epoxides or oxetanes in good yields.
