115225-33-7Relevant articles and documents
Weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis
Park, Jin,Park, Sehoon,Jang, Gwang Seok,Kim, Ran Hui,Jung, Jaehoon,Woo, Sang Kook
supporting information, p. 9995 - 9998 (2021/10/06)
The selective rearrangement of oxaziridines to amidesviaa single electron transfer (SET) pathway is unexplored. In this study, we present a weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis. The developed method shows excellent functional group tolerance with a broad substrate scope and good to excellent yields. Furthermore, control experiments and density functional theory (DFT) calculations are performed to gain insight into the reactivity and selectivity.
An environmentally friendly oxidation system for the selective oxygenation of aldimines to oxaziridines with anhydrous TBHP and alumina-supported MoO 3 as a recyclable heterogeneous catalyst
Singhal, Sweety,Jain, Suman L.,Prasad,Sain, Bir
, p. 2051 - 2054 (2008/02/04)
A highly efficient and selective protocol for the oxygenation of various aldimines to oxaziridines, which proceeds in excellent yields with enhanced selectivity by using alumina-supported M0O3 as a recyclable heterogeneous catalyst and anhydrous TBHP as the ultimate oxidant, is described. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
PHASE-TRANSFER CATALYTIC SYNTHESIS OF OXAZIRIDINES
Bulachkova, A. I.,Koldobskii, G. I.,Drozdetskii, A. G.,Tereshchenko, G. F.
, p. 632 - 636 (2007/10/02)
The phase-transfer catalytic oxidation of imines is a general method for the preparation of oxaziridines with various structures.Oxone (2KHSO5*KHSO4*K2SO4) and perbenzoic acid in combination with such phase-transfer catalysts as benzyltriethylammonium chl