115237-87-1Relevant academic research and scientific papers
Intramolecular Anodic Carbon-Carbon Bond-Forming Reactions of Oxidized Phenol Intermediates Leading to Spirodienones. Structural Effects on Reactivity and Evidence for a Phenoxonium Ion Intermediate
Swenton, John S.,Carpenter, Kenneth,Chen, Ying,Kerns, Michael L.,Morrow, Gary W.
, p. 3308 - 3316 (2007/10/02)
Anodic oxidation of 4-phenylphenol in methanol leads to 4-methoxy-4-phenylcyclohexa-2,5-dienones whereas anodic oxidation of 4-(2-alkenylphenyl)-phenols leads to spirocyclic 2,5-cyclohexadienones in competition with methanol addition to the 4-position.Usi
SPIRO-ANNULATED CYCLOHEXA-2,5-DIENONES VIA ELECTROOXIDATION OF P-ARYL PHENOLS A NOVEL MODE OF ANODIC CARBON-CARBON BOND FORMATION
Morrow, Gary W.,Swenton, John S.
, p. 5445 - 5448 (2007/10/02)
Intramolecular trapping of the reactive intermediate from anodic oxidation of 2'-alkenyl substituted p-aryl phenols, followed by solvent capture, affords 4-aryl-4-alkyl-cyclohexa-2,5-dienones.
