115243-95-3

Upstream product

• 28713-39-5 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 115243-97-5 (5S)-1,2-O-isopropylidene-3-O-benzyl-5-(2-thiazolyl)-α-D-xylo-pentofuranose 
• 100-39-0 benzyl bromide 
• 101996-88-7 3-O-benzyl-5-C-(2-furyl)-1,2-O-isopropylidene-α-D-glucopentofuranose 
• 182298-29-9 (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-[(E)-pyrrolidin-1-ylimino]-ethanol 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 182298-39-1 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-gluco-hexodialdo-1,4-furanose N,N-butylenehydrazone 

Downstream Products

• 115243-98-6 (1S,2R)-2-Benzyloxy-2-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-thiazol-2-yl-ethanol 
• 115243-99-7 (1R,2R)-2-Benzyloxy-2-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-thiazol-2-yl-ethanol 
• 28713-39-5 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 162179-07-9 3-O-benzyl-1,2-O-isopropylidene-5,6,7,8-tetradeoxy-α-D-xylo-oct-5(E),7-dieno-1,4-furanose 
• 146176-88-7 C₁₀₈H₁₁₀N₄O₂₀ 

Relevant academic research and scientific papers

A convenient route to enantiomerically pure, conjugated dienes from sugar allyltin derivatives

The transformation of sugar allyltin derivatives into enantiomerically pure dienes (R*-CH=CH-CH=CH2) is presented. The internal double bond with the trans-configuration is formed regardless of the configuration of the starting sugar allyltin. Copyright (C) 2000 Elsevier Science Ltd.

Stereospecific addition of formaldehyde dialkylhydrazones to sugar aldehydes. Synthesis of cyanohydrins and α-hydroxy aldehydes

Formaldehyde dialkylhydrazones smoothly add to sugar aldehydes without any need of promoter or catalyst. α-Hydroxy dialkylhydrazones, which are obtained in good yields and high stereoselectivities, have been successfully transformed in cyanohydrins by treatment with magnesium monoperoxyphtalate (MMPP) and in O-protected α-hydroxy aldehydes by ozonolysis or HCl mediated hydrolysis. No racemization was observed in the cleavage of the dialkylhydrazone group.

STEREOSPECIFIC HOMOLOGATION OF D-XYLO AND D-GALACTO DIALDOSES BY 2-TRIMETHYLSILYLTHIAZOLE

Homologation of the title dialdoses is carried out by diastereogenic addition of 2-trimethylsilylthiazole (1) to the side-chain aldehyde and unmasking the formyl group from thiazole ring; further addition of 1 to the resulting homologated dialdoses exhibi