1152437-72-3Relevant academic research and scientific papers
Gold(I)-catalyzed enantioselective [4 + 2]-cycloaddition of allene-dienes
Gonzalez, Ana Z.,Dean Toste
supporting information; experimental part, p. 200 - 203 (2010/05/18)
"Chemical Equation Presented" An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of alienes and dienes is reported. The reactions allow for the asymmetric synthesis of frans-hexahydroindenes and pyrrolidine products using C3/
Gold-catalyzed [4C+2C] cycloadditions of allenedienes, including an enantioselective version with new phosphoramidite-based catalysts: Mechanistic aspects of the divergence between [4C+3C] and [4C+2C] pathways
Alonso, Isaac,Trillo, Beatriz,Lopez, Fernando,Montserrat, Sergi,Ujaque, Gregori,Castedo, Luis,Lledos, Agusti,Mascarenas, Jose L.
supporting information; experimental part, p. 13020 - 13030 (2009/12/08)
Gold(I) complexes featuring electron acceptor ligands such as phosphites and phosphoramidites catalyze the [4C+2C] intramolecular cycloaddition of allenedienes. The reaction is chemo- and stereoselective, and provides trans-fused bicyclic cycloadducts in
