115244-01-4

Upstream product

• 91861-00-6 6-O-benzyl-1,2:3,4-di-O-isopropylidene-α-D-galacto-D-glycero-heptodialdo-1,5-pyranose 
• 115244-00-3 (6S)-1,2:3,4-di-O-isopropylidene-6-(2-thiazolyl)-α-D-galacto-hexo-1,5-pyranose 
• 118377-18-7 (6S)-6-O-benzyl-1,2:3,4-di-O-isopropylidene-6-(2-thiazolyl)-α-D-galacto-hexo-1,5-pyranose 
• 4933-77-1 (3aR,5S,5aR,8aS,8bR)-2,2,7,7-Tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-carbaldehyde 
• 79265-30-8 2-(trimethylsilyl)thiazole 
• 91861-00-6 6-O-benzyl-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-heptodialdo-1,5-pyranose 

Downstream Products

• 118377-24-5 (1R,2R,3R,4R)-2,3,4-Tris-benzyloxy-4-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-yl)-1-thiazol-2-yl-butan-1-ol 
• 118377-24-5 (9S)-6,7,8-tri-O-benzyl-1,2:3,4-di-O-isopropylidene-9-(2-thiazolyl)-α-D-galacto-D-ribo-nonulo-1,5-pyranose 
• 118377-21-2 (1R,2R,3R)-2,3-Bis-benzyloxy-3-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-yl)-1-thiazol-2-yl-propan-1-ol 
• 118377-21-2 (8S)-6,7-di-O-benzyl-1,2:3,4-di-O-isopropylidene-8-(2-thiazolyl)-α-D-galacto-D-erythro-octulo-1,5-pyranose 
• 118377-22-3 (8S)-6,7,8-tri-O-benzyl-1,2:3,4-di-O-isopropylidene-8-(2-thiazolyl)-α-D-galacto-D-erythro-octulo-1,5-pyranose 
• 118377-23-4 6,7,8-tri-O-benzyl-1,2:3,4-di-O-isopropylidene-α-D-galacto-D-ribo-nonodialdo-1,5-pyranose 
• 118377-20-1 6,7-di-O-benzyl-1,2:3,4-di-O-isopropylidene-α-D-galacto-D-erythro-octodialdo-1,5-pyranose 
• 118377-19-8 (7S)-6,7-di-O-benzyl-1,2:3,4-di-O-isopropylidene-7-(2-thiazolyl)-α-D-galacto-D-glycero-heptulo-1,5-pyranose 

Relevant academic research and scientific papers

Iterative, Stereoselective Homologation of Chiral Polyalkoxy Aldehydes Employing 2-(Trimethylsilyl)thiazole as a Formyl Anion Equivalent. The Thiazole Route to Higher Carbohydrates

A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide (2a), L-threose acetonide (2b), and dialdogalactopyranose diacetonide (2h) into higher homologues up to C9, C7, and C

STEREOSPECIFIC HOMOLOGATION OF D-XYLO AND D-GALACTO DIALDOSES BY 2-TRIMETHYLSILYLTHIAZOLE

Homologation of the title dialdoses is carried out by diastereogenic addition of 2-trimethylsilylthiazole (1) to the side-chain aldehyde and unmasking the formyl group from thiazole ring; further addition of 1 to the resulting homologated dialdoses exhibi