1152500-47-4Relevant academic research and scientific papers
Synthesis of polysubstituted pyrroles via Pd-catalyzed oxidative alkene C-H bond arylation and amination
Zheng, Jia,Huang, Liangbin,Huang, Chuyu,Wu, Wanqing,Jiang, Huanfeng
, p. 1235 - 1242 (2015/01/30)
A novel Pd(II)-catalyzed oxidative approach to construct polysubstituted pyrroles from N-homoallylicamines and arylboronic acids was developed. This transformation is supposed to proceed through cascade formation of C-C and C-N bonds via oxidative arylation of unactive alkenes, followed by intramolecular aza-Wacker cyclization.
Complex polycyclic scaffolds by metathesis rearrangement of Himbert arene/allene cycloadducts
Lam, Jonathan K.,Schmidt, Yvonne,Vanderwal, Christopher D.
supporting information, p. 5566 - 5569 (2013/01/15)
The intramolecular arene/allene cycloaddition first described 30 years ago by Himbert and Henn permits rapid access to strained polycyclic compounds. Alkene metathesis processes cleanly rearrange appropriately substituted cycloadducts into complex, functi
