115319-74-9

Basic information

• Product Name: 4-hydroxybenzyl 2-(2-methoxyethoxy)ethyl ether
• Synonyms: 4-hydroxybenzyl 2-(2-methoxyethoxy)ethyl ether
• CAS NO: 115319-74-9
• Molecular Weight: 226.273
• Mol File: 115319-74-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-hydroxybenzyl 2-(2-methoxyethoxy)ethyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 4-hydroxybenzyl 2-(2-methoxyethoxy)ethyl ether(115319-74-9)
• EPA Substance Registry System: 4-hydroxybenzyl 2-(2-methoxyethoxy)ethyl ether(115319-74-9)

Safety Data

• Hazardous Substances Data: 115319-74-9(Hazardous Substances Data)

Upstream product

• 111-77-3 2-(2-methoxyethoxy)ethyl alcohol 
• 623-05-2 (4-hydroxyphenyl)methanol 

Downstream Products

• 111-77-3 2-(2-methoxyethoxy)ethyl alcohol 

Relevant articles and documents

Compounds and methods of arylmethylation (benzylation) as protection for alcohol groups during chemical synthesis

A process for benzylating an alcohol includes mixing 2-benzyloxy-1-methylpyridinium triflate in an aromatic hydrocarbon solvent having a predetermined boiling point; adding an acid scavenger to the mixture; combining the alcohol to be benzylated with the mixture; reacting the alcohol with the 2-benzyloxy-1-methylpyridinium triflate by heating above ambient temperature to generate the benzylated alcohol; and separating the benzylated alcohol from the mixture.

ON THE METALATION OF PHENOLIC COMPOUNDS: READY ACCESS TO HIGHLY SUBSTITUTED PHENOLS.

The direct metalation of several p-hydroxybenzylmethyl ethers has been studied.Those substrates possesing an electron-withdrawing group in a 1,3 relationship with the coordinating (-CH2OMe) group underwent regioselective metalation by the action of n-BuLi/THF.Highly substituted phenols can thus be readily prepared.