1153285-12-1

Basic information

• Product Name: Methyl 2,4-dichloro-5-fluoro-3-nitrobenzoate
• Synonyms: Methyl 2,4-dichloro-5-fluoro-3-nitrobenzoate
• CAS NO: 1153285-12-1
• Molecular Formula: C₈H₄Cl₂FNO₄
• Molecular Weight: 268.0260632
• EINECS: -0
• Mol File: 1153285-12-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 357.5±42.0 °C(Predicted)
• Appearance: /
• Density: 1.602±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Methyl 2,4-dichloro-5-fluoro-3-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,4-dichloro-5-fluoro-3-nitrobenzoate(1153285-12-1)
• EPA Substance Registry System: Methyl 2,4-dichloro-5-fluoro-3-nitrobenzoate(1153285-12-1)

Safety Data

• Hazardous Substances Data: 1153285-12-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 106809-14-7 2,4-dichloro-5-fluoro-3-nitro-benzoic acid 
• 4731-65-1 tris(o-methoxyphenyl)phosphine 

Downstream Products

• 1159908-24-3 C₈H₆Cl₂FNO₂ 

Relevant articles and documents

Rhodium-Catalyzed Double Alkyl-Oxygen Bond Cleavage: An Alkyl Transfer Reaction from Bis/Tris(o-alkyloxyphenyl)phosphine to Aryl Acids

An unprecedented rhodium-catalyzed selective cleavage of double alkyl-oxygen bonds of bis/tris(o-alkyloxyphenyl)phosphine has been realized, in which P atom functions as a directing group and simple aryl acids are the methyl group acceptor to provide methyl esters and a quaternary phosphonium salt. The preliminary mechanism was investigated via an 18O labeling experiment and stoichiometric reaction between a Rh-A crystal and an aromatic acid.