115333-56-7Relevant academic research and scientific papers
Diterpenoid Total Synthesis, XXXI. Synthesis and Absolute Configuration of (-)-Stypoldione, a Metabolite of Stypopodium zonale
Mori, Kenji,Koga, Yasuo
, p. 1755 - 1764 (2007/10/03)
(S)-3-Hydroxy-2,2-dimethylcyclohexanone (2) was converted to (-)-stypoldione (1), the ichthyotoxic and cytotoxic metabolite of the brown alga Stypopodium zonale.The present synthesis established the absolute configuration of (-)-stypoldione as depicted in
SYNTHESIS OF (+)-BAIYUNOL, THE DITERPENE AGLYCONE OF THE SWEET GLYCOSIDE BAIYUNOSIDE
Mori, Kenji,Komatsu, Makoto
, p. 3409 - 3412 (2007/10/02)
A chiral synthesis of (+)-baiyunol, the labdane-type diterpene aglycone of the sweet glycoside baiyunoside, was achieved starting from (S)-3-hydroxy-2,2-dimethylcyclohexanone.
