115369-24-9Relevant academic research and scientific papers
Stereoselective syntheses of rolliniastatin 1, rollimembrin, and membranacin
Keum, Gyochang,Hwang, Cheol Hee,Kang, Soon Bang,Kim, Youseung,Lee, Eun
, p. 10396 - 10399 (2007/10/03)
A radical cyclization of β-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocol was successfully applied to the synthesis of the threol cis/threol cis/erythro bis-oxolane moiety in rolliniastatin 1 (1), rollimembrin (2), and membranacin (3).
SYNTHESIS OF A MARINE POLYETHER TOXIN, OKADAIC ACID (2) -- SYNTHESIS OF SEGMENT B
Ichikawa, Yoshiyasu,Isobe, Minoru,Goto, Toshio
, p. 4749 - 4758 (2007/10/02)
The central synthetic segment B for okadaic acid comprises the carbons from 15 through 27 including 6 asymmetric carbons.Its synthesis started from a D-glucose derivative, whose carbon was extended twice for the six and five membered etherial ring formati
