115385-10-9Relevant academic research and scientific papers
Molecular structures and reactivities of digermiranes and azadigermiridines
Tsumuraya, Takeshi,Sato, Sadao,Ando, Wataru
, p. 2061 - 2067 (2008/10/08)
Reaction of tetrakis(2,6-diethylphenyl)digermene (2) with diazomethane produces 1,1,2,2-tetrakis(2,6-diethylphenyl)digermirane (3). The photolysis of 3 with a high-pressure mercury lamp yields germene 13 and germylene 14. The digermirane 3 reacts with pyridine N-oxide, sulfur, and selenium to yield the insertion products of O, S, and Se into the germanium-germanium bond. 2,2,3,3-Tetrakis(2,6-diethylphenyl)-1-phenylazadigermiridine (5) is also prepared by the reaction of 2 with phenyl azide. The structures of the digermirane 3 and the azadigermiridine 5 have been determined by X-ray crystal analyses. Both 3 and 5 have relatively short germanium-germanium bond distances of 2.379 (1) ? and nearly planar arrangements of CAr, CAr, and Ge atoms around each germanium.
Digermirane and azadigermiridine: Synthesis and reactions
Ando, Wataru,Tsumuraya, Takeshi
, p. 1882 - 1883 (2008/10/08)
1,1,2,2-Tetrakis(2,6-diethylphenyl)digermirane (3) was prepared by the reaction of tetrakis(2,6-diethylphenyl)digermene (2) with diazomethane. The photolysis of 3 with a high-pressure mercury lamp yields germene 4 and germylene 5. The digermirane 3 reacts with pyridine N-oxide, sulfur, and selenium to yield the insertion products of O, S, and Se into the germanium-germanium bond. 2,2,3,3-Tetrakis(2,6-diethylphenyl)azadigermiridine (12) was prepared by the reaction of 2 with phenyl azide.
