115385-08-5

Upstream product

• 186581-53-3 diazomethane 
• 94833-02-0 hexakis(2,6-diethylphenyl)cyclotrigermane 

Downstream Products

• 115385-10-9 bis(2,6-diethylphenyl)methoxymethylgermane 
• 98583-16-5 bis(2,6-diethylphenyl)methoxygermane 
• 98583-14-3 bis(2,6-diethylphenyl)(Me)2(1-germacyclopent-3-ene) 
• 115385-12-1 tetrakis(2,6-diethylphenyl)-1,2,4-thiadigermetane 
• 115385-11-0 tetrakis(2,6-diethylphenyl)-1,2,4-oxadigermetane 
• 115406-97-8 tetrakis(2,6-diethylphenyl)-1,2,4-selenadigermetane 
• 122270-73-9 {C₆H₃(C₂H₅)2}2Ge(H)CH₂Ge{C₆H₃(C₂H₅)2}2CHCHCO₂CH₃ 
• 122270-72-8 {C₆H₃(C₂H₅)2}2GeCH₂Ge{C₆H₃(C₂H₅)2}2CHCH 
• 122293-22-5 {C₆H₃(C₂H₅)2}2GeCH₂Ge{C₆H₃(C₂H₅)2}2Pd(P(C₆H₅)3)2 
• 122270-74-0 Cl(C₆H₃(C₂H₅)2)2GeCH₂Ge(C₆H₃(C₂H₅)2)2Cl 
• 122270-71-7 {(C₂H₅)2C₆H₃}2GeCH₂Ge{C₆H₃(C₂H₅)2}2C(CO₂CH₃)C(CO₂CH₃) 
• 122270-77-3 {C₆H₃(C₂H₅)2}2GeCH₂Ge{C₆H₃(C₂H₅)2}2PdP(C₆H₅)3 
• 141366-37-2 3,3,5,5-tetrakis(2,6-diethylphenyl)-1,2,3,5-dioxadigermolane 

Relevant academic research and scientific papers

Molecular structures and reactivities of digermiranes and azadigermiridines

Reaction of tetrakis(2,6-diethylphenyl)digermene (2) with diazomethane produces 1,1,2,2-tetrakis(2,6-diethylphenyl)digermirane (3). The photolysis of 3 with a high-pressure mercury lamp yields germene 13 and germylene 14. The digermirane 3 reacts with pyridine N-oxide, sulfur, and selenium to yield the insertion products of O, S, and Se into the germanium-germanium bond. 2,2,3,3-Tetrakis(2,6-diethylphenyl)-1-phenylazadigermiridine (5) is also prepared by the reaction of 2 with phenyl azide. The structures of the digermirane 3 and the azadigermiridine 5 have been determined by X-ray crystal analyses. Both 3 and 5 have relatively short germanium-germanium bond distances of 2.379 (1) ? and nearly planar arrangements of CAr, CAr, and Ge atoms around each germanium.

Digermirane and azadigermiridine: Synthesis and reactions

1,1,2,2-Tetrakis(2,6-diethylphenyl)digermirane (3) was prepared by the reaction of tetrakis(2,6-diethylphenyl)digermene (2) with diazomethane. The photolysis of 3 with a high-pressure mercury lamp yields germene 4 and germylene 5. The digermirane 3 reacts with pyridine N-oxide, sulfur, and selenium to yield the insertion products of O, S, and Se into the germanium-germanium bond. 2,2,3,3-Tetrakis(2,6-diethylphenyl)azadigermiridine (12) was prepared by the reaction of 2 with phenyl azide.