115394-52-0Relevant academic research and scientific papers
Reduction of Co-ordinated Carbon Dioxide to Carbon Mo oxide via Protonation by Thiols and other Broensted Acids promoted by Ni-Systems: A Contribution to the Understanding of the Mode of Action of the Enzyme Carbon Monoxide Dehydrogenase
Aresta, Michele,Quaranta, Eugenio,Tommasi, Immacolata
, p. 450 - 452 (1988)
Carbon dioxide co-ordinated to Ni0 is easily reduced to bound carbon monoxide by R-SH (R=H, alkyl, benzyl, phenyl, and substituted phenyl) and other Broensted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.
