Reduction of Co-ordinated Carbon Dioxide to Carbon Mo oxide via Protonation by Thiols and other Broensted Acids promoted by Ni-Systems: A Contribution to the Understanding of the Mode of Action of the Enzyme Carbon Monoxide Dehydrogenase

DOI: 10.1039/c39880000450

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 450 - 452 (1988)

Update date:2022-07-30

Topics:

Authors:

Aresta, Michele

Quaranta, Eugenio

Tommasi, Immacolata

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000450

Carbon dioxide co-ordinated to Ni⁰ is easily reduced to bound carbon monoxide by R-SH (R=H, alkyl, benzyl, phenyl, and substituted phenyl) and other Broensted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.

Full text of DOI:10.1039/c39880000450

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(P(C₆H₁₁)3)2Ni(SH)2

Cas No:115394-52-0

R&D Labs maybe for 115394-52-0

Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu

Relevant to this article

Unusual Structure in Meisenheimer Complex Formation from the Highly Electrophilic 4,6-Dinitrobenzofuroxan

Doi:10.1021/jo00253a044
(1988)
The enantioselective addition of 1-fluoro-1-nitro(phenylsulfonyl)methane to isatin-derived ketimines

Doi:10.1039/c7ob02408h
(2017)
Rhodium-catalyzed organothio exchange reaction of α-organothioketones with disulfides

Doi:10.1248/cpb.58.1349
(2010)
Organoboron-Promoted Regioselective Glycosylations in the Synthesis of a Saponin-Derived Pentasaccharide from Spergularia ramosa

Doi:10.1021/acs.joc.5b00950
(2015)
Simple synthesis of conjugated all-(E)-polyenic aldehydes, ketones, and esters using chemoselective cross-metathesis and an iterative sequence of reactions: Application to the synthesis of navenone B

Doi:10.1055/s-0028-1087953
(2009)
Discovery of low nanomolar and subnanomolar inhibitors of the mycobacterial β-carbonic anhydrases Rv1284 and Rv3273

Doi:10.1021/jm9004016
(2009)

Article Doi