Reduction of Co-ordinated Carbon Dioxide to Carbon Mo oxide via Protonation by Thiols and other Broensted Acids promoted by Ni-Systems: A Contribution to the Understanding of the Mode of Action of the Enzyme Carbon Monoxide Dehydrogenase

DOI: 10.1039/c39880000450

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 450 - 452 (1988)

Update date:2022-07-30

Topics:

Authors:

Aresta, Michele

Quaranta, Eugenio

Tommasi, Immacolata

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000450

Carbon dioxide co-ordinated to Ni⁰ is easily reduced to bound carbon monoxide by R-SH (R=H, alkyl, benzyl, phenyl, and substituted phenyl) and other Broensted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.

Full text of DOI:10.1039/c39880000450

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(P(C₆H₁₁)3)2Ni(SH)2

Cas No:115394-52-0

R&D Labs maybe for 115394-52-0

Shijiazhuang Yesheng Chemical Technology Co., Ltd

Contact:18031146013

Address:Hebei Xinji Xincheng
Henan Sinotech Import&Export Corporation

website:http://www.hasinotech.com

Contact:86-371-86181678

Address:No. 260, Dongming Road,Jinshui District
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
Dragon Chemical Co., Ltd.

Contact:0571-

Address:zhejing
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:13th Floor, Xinbao Technology Industrial Park, No. 2 Ruixiang Road, Huangpu District, Guangzhou,Guangdong,China

Relevant to this article

Unusual Structure in Meisenheimer Complex Formation from the Highly Electrophilic 4,6-Dinitrobenzofuroxan

Doi:10.1021/jo00253a044
(1988)
The enantioselective addition of 1-fluoro-1-nitro(phenylsulfonyl)methane to isatin-derived ketimines

Doi:10.1039/c7ob02408h
(2017)
Rhodium-catalyzed organothio exchange reaction of α-organothioketones with disulfides

Doi:10.1248/cpb.58.1349
(2010)
Organoboron-Promoted Regioselective Glycosylations in the Synthesis of a Saponin-Derived Pentasaccharide from Spergularia ramosa

Doi:10.1021/acs.joc.5b00950
(2015)
Simple synthesis of conjugated all-(E)-polyenic aldehydes, ketones, and esters using chemoselective cross-metathesis and an iterative sequence of reactions: Application to the synthesis of navenone B

Doi:10.1055/s-0028-1087953
(2009)
Discovery of low nanomolar and subnanomolar inhibitors of the mycobacterial β-carbonic anhydrases Rv1284 and Rv3273

Doi:10.1021/jm9004016
(2009)

Article Doi