Reduction of Co-ordinated Carbon Dioxide to Carbon Mo oxide via Protonation by Thiols and other Broensted Acids promoted by Ni-Systems: A Contribution to the Understanding of the Mode of Action of the Enzyme Carbon Monoxide Dehydrogenase

DOI: 10.1039/c39880000450

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 450 - 452 (1988)

Update date:2022-07-30

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Authors:

Aresta, Michele

Quaranta, Eugenio

Tommasi, Immacolata

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Article abstract of DOI:10.1039/c39880000450

Carbon dioxide co-ordinated to Ni⁰ is easily reduced to bound carbon monoxide by R-SH (R=H, alkyl, benzyl, phenyl, and substituted phenyl) and other Broensted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.

Full text of DOI:10.1039/c39880000450

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