1154047-85-4

Upstream product

• 501-65-5 diphenyl acetylene 
• 806-58-6 1,2,4-triphenylnaphthalene 
• 122048-53-7 10-bromobenzochrysene 
• 98-80-6 phenylboronic acid 
• 573-17-1 9-bromophenanthrene 
• 24892-82-8 1-bromo-2-(1-phenylpropen-1-yl)benzene 

Relevant academic research and scientific papers

Direct Synthesis of Napthalenes by Nickel-Catalyzed Cascade Cyclization of o-Vinyl Chlorobenzenes with Internal Alkynes

An efficient nickel-catalyzed arylnickelation of alkyne/Heck cyclization of challenging o-vinyl chlorobenzenes with internal alkynes has been developed. This protocol enables synthesis of a wide variety of substituted naphthalenes in a cascade process from readily available starting materials. Mechanistic studies indicate the radical pathway is not involved in the cascade catalytic system.

Preparation method of fused ring compound

The invention discloses a preparation method of a fused ring compound III. The preparation method comprises the following step: in a solvent and in the presence of palladium acetate, alkali and a ligand, carrying out a reaction shown in the specification on a compound I and a compound II to obtain a compound III. The preparation method disclosed by the invention is relatively good in compatibilitywith a substrate, various polycyclic aromatic hydrocarbon compounds can be simply obtained in a short period of time through convergent synthesis, and particularly, heteroatom-containing polycyclic aromatic hydrocarbon shows extremely excellent regioselectivity.

Sequential Cross-Coupling/Annulation of ortho-Vinyl Bromobenzenes with Aromatic Bromides for the Synthesis of Polycyclic Aromatic Compounds

A sequential cross-coupling/annulation of ortho-vinyl bromobenzenes with aromatic bromides was realized, providing a direct and modular approach to access polycyclic aromatic compounds. A vinyl-coordinated palladacycle was proposed as the key intermediate for this sequential process. Excellent chemoselectivity and regioselectivity were observed in this transformation. The practicability of this method is highlighted by its broad substrate scope, excellent functional group tolerance, and rich transformations associated with the obtained products.

MONOBENZOCHRYSENE DERIVATIVE, ORGANIC ELECTROLUMINESCENT DEVICE MATERIAL CONTAINING THE SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE ORGANIC ELECTROLUMINESCENT DEVICE MATERIAL

A monobenzochrysene derivative shown by the following formula (1): wherein R1 to R14 are independently a hydrogen atom or a substituent, and at least one of R1 to R14 is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms which does not contain an anthracene skeleton and a benzo[g]chrysene skeleton or a substituted or unsubstituted heteroaryl group having 5 to 50 ring carbon atoms which does not contain an anthracene skeleton and a benzo[g]chrysene skeleton, excluding the case where R8 and R9 are unsubstituted phenyl groups and R1 to R7 and R10 to R14 are hydrogen atoms and the case where R9 is an unsubstituted phenyl group and R1 to R8 and T10 to R14 are hydrogen atoms.