115411-07-9Relevant academic research and scientific papers
Catalytic carbopalladation of ο-methylenebicycloalkanes
Donaldson, William A.,Brodt, Christine A.
, p. C33 - C36 (1987)
ο-Methylenebicycloalkanes undergo carbopalladation via cleavage of the C(1)-C(2) cyclopropane bond.The resultant ?-butenyl complexes decompose via β-hydride elimination to afford the 1-cycloalkenylstyrene products.
On the Twofold Heck Reaction of 4-Vinylcyclohexene and p-Dihalobenzenes
Lorenz, Peter,Becher, Diana,Steinborn, Dirk,Poetsch, Eike,Akermark, Bjoern
, p. 375 - 378 (2007/10/02)
The palladium-catalyzed reaction of iodobenzene, p-haloiodobenzenes (p-C6H4IX'; X' = F, Cl, Br, I) and p-dibromobenzene with 4-vinylcyclohexene (Heck arylation reaction of olefins) was investigated with Pd(OAc)2/PR3/Et3N (R = phenyl, o-tolyl) as a classic
CARBOPALLADATION DES ALKYLIDENECYCLOPROPANES-I; CAPTURE INTERMOLECULAIRE DE L'ORGANOPALLADIQUE INTERMEDIAIRE
Fournet, Guy,Balme, Genevieve,Gore, Jacques
, p. 5809 - 5820 (2007/10/02)
The reaction of methylenecyclopropane and 1-cyclopropylidene pentane with iodobenzene or 2-bromopropene and a delocalized anion (issued from malonate or from a β-sulfonyl ester) in the presence of catalytic amounts of a palladium (0) complex leads to conj
