115437-14-4Relevant academic research and scientific papers
New synthesis of 2-methyleneaziridines and 2-methyleneazetidines by dimethyl titanocene mediated methylenation of α- and β-lactams
Abbaspour Tehrani, Kourosch,De Kimpe, Norbert
, p. 1975 - 1978 (2007/10/03)
2-Methyleneaziridines and 2-methyleneazetidines were synthesized via a titanium mediated olefination procedure starting from the corresponding α- lactams and β-lactams. (C) 2000 Elsevier Science Ltd.
A NEW METHOD FOR THE PREPARATION OF β-(ALKYLAMINO)-CARBONYL COMPOUNDS BY REARRANGEMENT OF β-CHLOROIMINES VIA AZETIDINE INTERMEDIATES
Sulmon, Paul,Kimpe, Norbert De,Schamp, Niceas
, p. 2937 - 2956 (2007/10/02)
The reaction of β-chloroimines with sodium methoxide in methanol gave rise to β-(alkylamino)- and β-(arylamino)-carbonyl compounds in high yield.The reaction mechanism for the generation of β-(alkylamino)- and β-(arylamino)-carbonyl compounds passes via a
A New Synthesis of N-Aryl-2-methyleneazetidines
Sulmon, Paul,Kimpe, Norbert De,Schamp, Niceas
, p. 4462 - 4465 (2007/10/02)
A novel straightforward synthesis of N-aryl-methyleneazetidines has been developed by reaction of N-aryl-β-chloro ketimines with potassium tert-butoxide.
