115463-62-2

Upstream product

• 186581-53-3 diazomethane 
• 120418-24-8 (2S,3S)-3-Hydroxy-2-(2-methylene-cyclohexyl)-butyric acid 
• 115463-61-1 (S)-3-Hydroxy-butyric acid cyclohex-1-enylmethyl ester 
• 54445-54-4 (+/-)-methyl 2-methylene-1-cyclohexaneacetate 
• 75-07-0 acetaldehyde 

Downstream Products

• 120418-27-1 (2R^*,3S^*,1'S^*)-(+/-)-2-(2'-Methylenecyclohexan-1'-yl)-1,3-butanediol 
• 120418-27-1 (2R^*,3S^*,1'R^*)-(+/-)-2-(2'-Methylenecyclohexan-1'-yl)-1,3-butanediol 
• 120418-27-1 (2R^*,3R^*,1'S^*)-(+/-)-2-(2'-Methylenecyclohexan-1'-yl)-1,3-butanediol 
• 120418-28-2 (4R^*,5R^*1'S^*)-(+/-)-2,2,4-Trimethyl-5-(2'-methylenecyclohexan-1'-yl)-1,3-dioxane 
• 120418-28-2 (4R^*,5S^*1'S^*)-(+/-)-2,2,4-Trimethyl-5-(2'-methylenecyclohexan-1'-yl)-1,3-dioxane 
• 120418-28-2 (4R^*,5R^*1'R^*)-(+/-)-2,2,4-Trimethyl-5-(2'-methylenecyclohexan-1'-yl)-1,3-dioxane 

Relevant academic research and scientific papers

Nucleophile-Selective Iodocyclizations: Butyrolactone versus Tetrahydrofuran Formation

Nucleophile selectivity in the electrophilic cyclization of substrates like 3 has been investigated in the context of efficient chemo- and stereoselective functionalization of 3-hydroxy-2-(2-methylenecyclohexan-1-yl)butyric acids (cf., 6-9) via iodocycliz

β-hydroxy Esters: (E)- versus (Z)-Enolate Geometry in Dianionic Claisen Rearrangements

Control elements operative in the β-hydroxy ester dianionic Claisen rearrangements are probed.Stereochemistry at Cβ dictates face selectivity at Cα and Cβ' in 1->2-5, but only to the extent that it controls ester enolate g