115463-61-1Relevant academic research and scientific papers
β-hydroxy Esters: (E)- versus (Z)-Enolate Geometry in Dianionic Claisen Rearrangements
Kurth, Mark J.,Beard, Richard L.
, p. 4085 - 4088 (1988)
Control elements operative in the β-hydroxy ester dianionic Claisen rearrangements are probed.Stereochemistry at Cβ dictates face selectivity at Cα and Cβ' in 1->2-5, but only to the extent that it controls ester enolate g
