115493-99-7Relevant academic research and scientific papers
Stereoselective β-C- and β-S-Glycosylation of 2-Deoxyribofuranose Derivatives Controlled by the 3-Hydroxy Protective Group
Ichikawa, Yuh-ichiro,Kubota, Hideki,Fujita, Ken'ichi,Okauchi, Tatsuo,Narasaka, Koichi
, p. 845 - 852 (1989)
β-C-2-Deoxyribofuranosides and β-S-2-deoxyribofuranosides are prepared stereoselectively from 1-O-acetyl-5-O-benzyl-3-O--2-deoxy-D-erythro-pentofuranose or the corresponding 3-O-(2-pyridylmethyl)pentofuranose N-oxide by the reacti
Stereoselective Preparation of β-C-Glycosides from 2-Deoxyribose Utilizing Neighboring Participation by 3-O-Methylsulfinylethyl Group
Narasaka, Koichi,Ichikawa, Yuh-ichiro,Kubota, Hideki
, p. 2139 - 2142 (2007/10/02)
Acid catalyzed reaction of 2-deoxy-3-O-methylsulfinylethylribofuranosyl acetate with silyl enol ethers proceeded stereoselectively, resulting in the predominant formation of the corresponding β-C-glycosides.
