Stereoselective β-C- and β-S-Glycosylation of 2-Deoxyribofuranose Derivatives Controlled by the 3-Hydroxy Protective Group

Article abstract of DOI:10.1246/bcsj.62.845

β-C-2-Deoxyribofuranosides and β-S-2-deoxyribofuranosides are prepared stereoselectively from 1-O-acetyl-5-O-benzyl-3-O-<2-(methylsulfinyl)ethyl>-2-deoxy-D-erythro-pentofuranose or the corresponding 3-O-(2-pyridylmethyl)pentofuranose N-oxide by the reacti