115528-58-0

Basic information

• Product Name: trans-[PdCl₂(NH₂PhCl)2]
• CAS NO: 115528-58-0
• Molecular Weight: 432.473
• Mol File: 115528-58-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[PdCl₂(NH₂PhCl)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[PdCl₂(NH₂PhCl)2](115528-58-0)
• EPA Substance Registry System: trans-[PdCl₂(NH₂PhCl)2](115528-58-0)

Safety Data

• Hazardous Substances Data: 115528-58-0(Hazardous Substances Data)

Upstream product

• 15020-99-2 cis-dichloro(ethylenediamine)palladium(II) 
• 904-70-1 N,N'-(1,4-phenylenebis(methan-1-yl-1-ylidene))bis(4-chloroaniline) 

Relevant articles and documents

Pd(II) catalyzed transformation of Schiff bases in complexes of the type trans-[PdCl2(NH2Ar-X)2] (X = H, CH3, Cl): Reactivity with aldehydes and Heck coupling reaction

Schiff bases of type (R-Ph-N=CH-Ph-CH=N-Ph-R), where, R = H (L 1), CH3 (L2) and Cl (L3), in presence of cis-[Pd(en)Cl2] or [Pd(DMSO)2Cl2] (en = 1,2-diaminoethane, DMSO = dimethylsulphoxide) give trans-[PdCl 2(NH2Ph)2] (1), trans-[PdCl2(NH 2PhCH3)2] (2) and trans-[PdCl 2(NH2PhCl)2] (3). The complexes are characterized using spectroscopic (IR, UV-vis and NMR) and X-diffraction techniques. The H-bonding interaction generates multinuclear supramolecular structure in complex (2) and (3). Complex (1) on reaction with benzaldehyde, salicylaldehyde and 4-carboxybenzaldehyde yields complexes of the type [PdCl2(PhN=CHPh)2] (4), [Pd(PhN=CHPhO)2] (5) and [PdCl2(PhN=CHPhCOOH)2] (6) respectively. The structures have been optimized using density functional theory at B3LYP level. Heck coupling reactions of bromobenzene with acrylonitrile and bromobenzene with ethyl acrylate in the presence of complexes (1), (2) and (3) have been carried out separately.