115580-01-3Relevant academic research and scientific papers
Control of γ vs. ε Regioselectivity on the Nucleophilic Addition of 2,4-Pentadienylstannane to Aldehydes by Lewis Acid Co-ordination
Naruta, Yoshinori,Nishigaichi, Yutaka,Maruyama, Kazuhiro
, p. 225 - 228 (1988)
The BF3-mediated nucleophilic addition of 2- and 4-methoxymethyl-2,4-pentadienylstannanes to aldehydes selectively gives the corresponding γ adducts, while the reaction with sterically hindered aldehydes affors the corresponding ε adducts regardless of the tin reagents applied.
