115586-65-7

Upstream product

• 727428-79-7 1-((R)-1,4-dioxaspiro[4.5]decan-2-yl)prop-2-en-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 115483-04-0 (2R,3R)-3-O-benzyl-4-pentene-1,2,3-triol 
• 100-39-0 benzyl bromide 
• 1292297-95-0 (2R)-2-[(1R)-1-(benzyloxy)prop-2-enyl]-1,4-dioxaspiro[4.5]decane 
• 108275-52-1 (R)-4-(1-Benzyloxy-allyl)-2,2-dimethyl-[1,3]dioxolane 
• 862972-77-8 (2R,3RS)-3-O-benzyl-4-pentene-1,2,3-triol 

Downstream Products

• 1229358-27-3 (2R,3R)-3-(benzyloxy)pent-4-en-2-ol 
• 1292297-96-1 (S)-[(2R,3R)-3-(benzyloxy)pent-4-en-2-yl] 4-(tert-butyldimethylsilyloxy)hept-6-enoate 
• 1292297-97-2 (S)-[(2R,3R)-3-(benzyloxy)pent-4-en-2-yl] 4-hydroxyhept-6-enoate 
• 1292297-98-3 (Z,5S,9R,10R)-9-(benzyloxy)-3,4,5,6,9,10-hexahydro-5-hydroxy-10-methyloxecin-2-one 
• 1229358-24-0 (2R,3R)-3-(benzyloxy)pent-4-en-2-yl (4S)-4-(benzyloxy)hept-6-enoate 
• 1229358-55-7 (5S,7Z,9R,10R)-5,9-bis(benzyloxy)-10-methyl-3,4,5,6,9,10-hexahydro-2H-oxecin-2-one 
• 115483-14-2 (5S,6R,7R)-6-benzyloxy-7-(tert-butyldimethylsiloxy)-2-(trimethylsilyl)bicyclo<3.3.0>oct-1-en-3-one 
• 115483-13-1 (5R,6R,7R)-6-benzyloxy-7-(tert-butyldimethylsiloxy)-2-(trimethylsilyl)bicyclo<3.3.0>oct-1-en-3-one 
• 115483-09-5 (3R,4R)-3-O-benzyl-4-O-(tert-butyldimethylsilyl)-7-trimethylsilyl-1-hepten-6-yne-3,4-diol 
• 115483-07-3 (3R,4R)-3-O-benzyl-7-trimethylsilyl-1-hepten-6-yne-3,4-diol 
• 115586-66-8 (3R,4R)-3-O-benzyl-4,5-epoxy-1-penten-3-ol 

Relevant academic research and scientific papers

Stereoselective Synthesis of Stagonolide G from d -Mannitol

A highly convergent, stereoselective total synthesis of a ten-membered lactone, stagonolide G, is described. Epoxide ring-opening with vinyl Grignard, Yamaguchi esterification and ring-closing metathesis are the key steps involved in the present approach.

Asymmetric total synthesis of stagonolide G

A simple asymmetric total synthesis of stagonolide G (1) is described. Asymmetric dihydroxylation, regioselective epoxide ring opening, and vinyl Grignard reactions are involved in generating the stereogenic centers C(4) and C(8), followed by Grubbs-II-ca

Asymmetric Synthesis of Carbacyclin Precursors by Pauson-Khand Cyclization

The carbacyclin precursors 11, 17, 18 have been prepared from the en-ynes 10, 15, 16 by cobalt-mediated cyclization (Pauson-Khand reaction) with varying degrees of diastereoselectivity.