1156005-43-4Relevant academic research and scientific papers
(N-{[4-(1,3-Benzothia-zol-2-yl)-anilino]carbonylmethyl-κO} iminodiacetato-κ3 O,N,O′)(1,10-phenanthroline- κ2 N,N′)cobalt(II) penta-hydrate
Lin, Guo-Wu,Wang, Yue,Lu, Tao
, p. m179-m181 (2008)
The title compound, [Co(C19H15N3O5S)(C12H8N2)]·5H2O, has a moderately distorted octa-hedral coordination environment composed of two N atoms of a 1,10-phenanthroline ligand and one N and three O atoms of an N-{[4-(1,3-benzo-thia-zol-2 - yl)-anilino]-carbonyl-methyl}-imino-diacetate (ZL-52-) ligand. The ring systems of the phenanthroline and ZL-5 2- ligands are coplanar and the complexes pack in layers parallel to the ab plane with the rings of adjacent complexes facing one another. The layers stack along the c axis and are linked by hydrogen bonds involving the five water solvent mol-ecules in the asymmetric unit and O atoms of the acetate groups of the ZL-52- ligand. This is believed to be the first crystal structure of a complex of a 2-(4-amino-phenyl)-benzo-thia-zole ligand.
Synthesis, structures and the biological activity study on the metal complexes of 2-(4-aminophenyl)benzothiazole derivative
Lin, Guo-Wu,Wang, Yue,Jin, Qiao-Mei,Yang, Tao-Tao,Song, Jie-Mei,Lu, Yi,Huang, Qing-Jie,Song, Ke,Zhou, Jun,Lu, Tao
, p. 35 - 42 (2012)
(2-(4-(Benzothiazole)phenyl)carbamoylmethyl)iminodiacetic acid (ZL-5) was synthesized and then its three metal complexes were prepared with structures determined by 1H NMR or X-ray. In all complexes, ZL-5 is deprotonated to generate the neutral
