1158398-82-3

Basic information

• Product Name: Ir(allyl)((S)-SEGPHOS)(m-nitrobenzoate(-H)-kappa.C,O)
• Synonyms: Ir(allyl)((S)-SEGPHOS)(m-nitrobenzoate(-H)-kappa.C,O)
• CAS NO: 1158398-82-3
• Molecular Weight: 1008.98
• Mol File: 1158398-82-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ir(allyl)((S)-SEGPHOS)(m-nitrobenzoate(-H)-kappa.C,O)(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(allyl)((S)-SEGPHOS)(m-nitrobenzoate(-H)-kappa.C,O)(1158398-82-3)
• EPA Substance Registry System: Ir(allyl)((S)-SEGPHOS)(m-nitrobenzoate(-H)-kappa.C,O)(1158398-82-3)

Safety Data

• Hazardous Substances Data: 1158398-82-3(Hazardous Substances Data)

Upstream product

• 12112-67-3 bis(1,5-cyclooctadiene)diiridium(I) dichloride 
• 591-87-7 Allyl acetate 
• 210169-54-3 (S)-SEGPHOS 
• 121-92-6 3-nitrobenzoic acid 

Relevant articles and documents

Enantioselective Ir-Catalyzed Bidirectional Reductive Coupling

In the presence of a chiral iridium complex, commercially available 3-chloro-2-chloromethyl-1-propene (1) was selectively activated for various reductive couplings. Depending on the reaction conditions it allows a selective mono- or bidirectional condensa

Total synthesis of bryostatin 7 via C-C bond-forming hydrogenation

The marine macrolide bryostatin 7 is prepared in 20 steps (longest linear sequence) and 36 total steps with five C-C bonds formed using hydrogenative methods. This approach represents the most concise synthesis of any bryostatin reported, to date.